GATE CE 2026 Set 2 — Question 63

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NAT+2 / -0HardpH, Turbidity, Hardness & AlkalinityWater QualityEnvironmental EngineeringChlorinationDrinking Water Treatment

Environmental Engineering → Drinking Water Treatment → Chlorination

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Question

The analysis of major cations and anions in a water sample collected from a city’s water supply is given below. Ions present in minor concentrations are not given.
AnionsClCl^-SO42SO_4^{2-}HCO3HCO_3^-CO32CO_3^{2-}
Concentration (mM)1.50.51.00.01
CationsNa+Na^+Ca2+Ca^{2+}Mg2+Mg^{2+}K+K^+
Concentration (mM)20.50.250.02
HClH++ClpK=3H2SO42H++SO42pK=3H2CO3H++HCO3pK=6.3HCO3H++CO32pK=10.3HOClH++OClpK=7.5\begin{aligned} HCl &\rightleftharpoons H^+ + Cl^- & pK &= -3 \\ H_2SO_4 &\rightleftharpoons 2H^+ + SO_4^{2-} & pK &= -3 \\ H_2CO_3 &\rightleftharpoons H^+ + HCO_3^- & pK &= 6.3 \\ HCO_3^- &\rightleftharpoons H^+ + CO_3^{2-} & pK &= 10.3 \\ HOCl &\rightleftharpoons H^+ + OCl^- & pK &= 7.5 \end{aligned}HOClHOCl (in %) present in the total free chlorine in the water is _____ (rounded off to the nearest integer).
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