Crystal structures and defects
Common metallic structures: BCC (e.g., α-iron), FCC (e.g., γ-iron, aluminum), and HCP (e.g., zinc). BCC has 2 atoms per unit cell, FCC has 4. Atomic packing factor is 0.68 for BCC and 0.74 for FCC. Point defects (vacancies), line defects (dislocations), and planar defects (grain boundaries) control plastic behavior.
Check yourself: Which crystal structure does the metal have at the temperature in question?
Phase diagrams and the lever rule
A binary phase diagram shows stable phases as functions of composition and temperature. In a two-phase region, the lever rule gives weight fractions: fraction of phase α = (C₀ - C_β)/(C_α - C_β), where C₀ is overall composition and C_α, C_β are the compositions at the phase boundaries (tie-line endpoints).
Check yourself: Are you reading compositions from the correct tie-line endpoints at the given temperature?
Iron-carbon system
Key phases: ferrite (α, BCC, low C solubility ≈ 0.022 wt%), austenite (γ, FCC, up to 2.14 wt% C), and cementite (Fe₃C, 6.67 wt% C). Eutectoid at 727 °C and 0.76 wt% C: austenite transforms to pearlite (ferrite + cementite). Hypoeutectoid steels (< 0.76% C) have proeutectoid ferrite; hypereutectoid steels have proeutectoid cementite.
Check yourself: Is the carbon content above or below the eutectoid composition?
Heat treatment of steels
Quenching austenite produces martensite (hard, brittle, BCT). Tempering reduces hardness and increases toughness. Annealing (slow cooling) produces equilibrium phases. Normalizing (air cooling) produces a finer pearlite than annealing. The TTT diagram shows transformation products as functions of time and temperature.
Check yourself: Was the cooling rate fast enough to suppress equilibrium transformations?
Mechanical testing and hardness
Tensile test yields: elastic modulus E (slope), yield strength σ_y (0.2% offset), ultimate tensile strength σ_ut, and percent elongation (ductility). Hardness tests (Brinell, Rockwell, Vickers) measure resistance to indentation. Hardness correlates with tensile strength for steels. Impact tests (Charpy, Izod) measure energy absorbed during fracture.
Check yourself: Does the test measure strength, ductility, hardness, or toughness?